Getting an existing Wordpress site to connect to database and be accessible

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Getting an existing Wordpress site to connect to database and be accessible
I have a site that I am moving from one server to another. I cant find the db user in the wp_users table. I have tried to using an existing admin wp_users to connect with the database but the users must be in a different table.
Need someone that find the database connection and get me to a point where I can log into the wordpress site using the admin credentials which are known.
Skills:
WordPress
, PHP
, MySQL
, HTML
, CSS

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